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One of the problems in deriving plutonium from spent reactor fuel rods, as the North Koreans apparently did, is that two isotopes of plutonium (239 and 240) have long half-lives, but only one of them (Pu239) is of use in nuclear bombs; the other is simply a contaminant. Since Pu240 is created from exposure of Pu239 to additional neutrons, the US and other nuclear states obtain their plutonium from from dedicated reactors where the Pu239 is removed as it is created, before significant Pu240 is formed. In a commercial reactor this isn't done, and the spent fuel rods contain significant quantities of the Pu240 contaminant (~20%). Since the two isotopes cannot be separated by chemical means, but only by time-consuming weight discrimination methods (e.g. centrifuge) which are exceedingly difficult with plutonium, no nuclear weapon states use the commercial reactor path in creating their weapon-grade plutonium.
From Wikipedia:
The isotope Pu-240 undergoes spontaneous fission very readily, and is produced when Pu-239 is exposed to neutrons. The presence of Pu-240 in a material limits its nuclear bomb potential since it emits neutrons randomly, increasing the difficulty of initiating accurately the chain reaction at the desired instant and thus reducing the bomb's reliability and power. Plutonium consisting of more than about 90% Pu-239 is called weapon-grade plutonium; plutonium obtained from commercial reactors generally contains at least 20% Pu-240 and is called reactor-grade plutonium.It seems quite likely that the NoKo bomb fizzled, at least in part, due to contamination of this sort. Of course, a poor implosion would have exacerbated the problem, but fuel contamination seems highly probable.Pu-240, while of little importance by itself, plays a crucial role as a contaminant in plutonium used in nuclear weapons. It spontaneously fissions at a high rate, and as a 1% impurity in Pu-239 will lead to unacceptably early initiation of a fission chain reaction in gun-type atomic weapons, blowing the weapon apart before much of its material can fission. Pu-240 contamination is the reason plutonium weapons must use an implosion design.
Poor separation of U235 from U238 in a uranium bomb would have similar issues, but it would take gross incompetence to screw that up.
Posted by Kevin Murphy at October 10, 2006 08:56 AM | TrackBackPoor separation of U235 from U238 in a uranium bomb would have similar issues, but it would take gross incompetence to screw that up.
As I've gone over and over this in my head, the idea that there are a few Heisenbergs in the Nork project has kept a little glimmer of my faith in humanity alive.
Posted by: Phelps at October 10, 2006 02:12 PMI'm not so certain.
Posted by: George at October 11, 2006 07:45 PMWell, I'm not so sure today, either. The Norks may be crazy, but they aren't stupid. It is however possible that they intentionally used some of their contaminated plutonium intentionally, testing their implosion device fully and expecting something of a dud.
After all they did have considerable refined U-235 from their secret 90's unranium enrichment program, which they could have used to create high-grade plutonium. But why use that?
Why not just test all they needed to test, while lulling the West into thinking they had screwed it up? Thus getting fewer sanctions than a fully successful test would have received.
Just a thought.
Posted by: Kevin Murphy at October 15, 2006 12:44 PM